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zinc iron flow battery system comprises several key components, including positive and negative electrodes, an electrolyte, and a membrane separator.. zinc iron flow battery system comprises several key components, including positive and negative electrodes, an electrolyte, and a membrane separator.. This review collectively presents the various aspects of the Zn–Fe RFB including the basic electrochemical cell chemistry of the anolyte and catholyte, and the different approaches considered for electrodes, electrolytes, membranes, and other cell components to overcome the above issues. This. . Zinc–iron redox flow batteries (ZIRFBs) possess intrinsic safety and stability and have been the research focus of electrochemical energy storage technology due to their low electrolyte cost. This review introduces the characteristics of ZIRFBs which can be operated within a wide pH range. . Given their low cost, exceptional performance, and wide availability of raw materials, zinc iron flow battery promise to revolutionize large-scale energy storage applications, significantly enhancing energy usage efficiency. The global energy landscape is undergoing a transformative shift, driven.